5. Avan Jogia

At the age of 18 and beginning to shed her innocent Disney rep, she was seen in a passionate make-out session together with Nickelodeon actor Avan Jogia. The photos of the raunchy scene were published by the Daily Mail, and at the time, Miley was on a break with her ex Liam. Jogia called her sweet, down-to-earth and lovely, but she ultimately fell out with Hemsworth shortly after.